Year 11 Chemistry Module 3 ⏱ ~35 min Lesson 1 of 12

Physical & Chemical Change

Every firework burst is a cascade of chemical changes — the same elements recombining into new substances, releasing light and energy in the process. Red from strontium, green from barium, blue from copper. The chemistry of change is happening all around you, every moment.

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Think First

You've probably seen iron rust and a candle burn. Both involve a metal or carbon reacting with oxygen. Here's the challenge: are rusting and burning the same type of change, or different? And is melting ice the same kind of change as burning wood?

Before you read on — write down what you think makes a change "chemical" versus "physical." What's your gut rule?

Type your initial response below — you will revisit this at the end of the lesson.

Write your initial response in your book. You will revisit it at the end of the lesson.

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📐

Key Principles — This Lesson

No calculation formulas — classification is conceptual
Key principle: Conservation of atoms — atoms are rearranged in chemical reactions, never created or destroyed Balancing rule: Total atoms on left = total atoms on right Test for chemical change: Is a new substance with different properties formed?
📖 Know

Key Facts

  • The five observable indicators of chemical change
  • Examples of physical and chemical changes
  • The Law of Conservation of Mass
💡 Understand

Concepts

  • Why new substance formation defines chemical change
  • How atoms are rearranged (not created/destroyed)
  • Why chemical equations must be balanced
✅ Can Do

Skills

  • Classify changes as physical or chemical with justification
  • Identify multiple indicators of chemical change in a scenario
  • Check whether a chemical equation is balanced
Key Terms — scan these before reading
Physical changeA change that alters the form or state of a substance without producing any new substance.
Chemical changeA change that produces one or more new substances with different chemical properties.
Law of Conservation of MassThe principle that total mass of reactants equals total mass of products in a chemical reaction.
Reversible reactionA reaction that can proceed in both forward and reverse directions under the same conditions.
Irreversible reactionA reaction that proceeds essentially to completion in one direction only.
Synthesis reactionA reaction where two or more reactants combine to form a single product.
🔍

Five Indicators of Chemical Change

You can't always see bonds breaking and forming — but chemical reactions leave observable clues. NSW HSC requires you to identify and explain five observable indicators.

FIVE INDICATORS OF CHEMICAL CHANGE 🎨 Colour Change New substances absorb different wavelengths of light Cu → green copper carbonate 💨 Gas Evolved Bubbling or fizzing indicates a new gaseous product Acid + carbonate → CO₂ gas ☁️ Precipitate Formed Cloudy solid appears when two solutions are mixed Pb(NO₃)₂ + KI → yellow PbI₂↓ 🌡️ Temperature Change Exothermic (heats up) or endothermic (cools down) Combustion (hot) NH₄NO₃ (cold) ⚗️ Solid Disappears Metal consumed in a reaction (not physical dissolving) Zn dissolves in HCl(aq)
HSC extended response tip: Name the specific indicator and explain what new substance caused it. "A yellow precipitate formed, indicating that lead iodide (PbI2) was produced" scores more marks than just "a precipitate formed."
Common error — temperature alone: A temperature change alone does not confirm a chemical change. Dissolving ammonium nitrate in water causes a temperature drop but is a physical change. Always look for multiple indicators or evidence of a new substance.
02

Modelling Atom Rearrangement & Conservation of Mass

Atoms are never created or destroyed in a chemical reaction — they are just reshuffled into new arrangements. This is the Law of Conservation of Mass, established by Antoine Lavoisier in the 1770s: the total mass of reactants equals the total mass of products in a closed system.

Consider the reaction of hydrogen gas with oxygen gas to form water:

H2 + O2 → H2O   ✗ UNBALANCED — 2 O on left, 1 O on right
2H2 + O2 → 2H2O   ✓ BALANCED — 4 H and 2 O on each side

Modelling this with coloured balls (atoms) and sticks (bonds) makes the rearrangement visible — the same atoms appear on both sides, just connected differently.

Balancing rule: When balancing equations, change coefficients (numbers in front of formulas) only — never change subscripts inside a formula. Changing H2O to H2O2 changes the substance entirely — that would be hydrogen peroxide, a different compound.
Common error — changing subscripts: Students often try to balance equations by changing subscripts rather than coefficients. Writing H2O3 instead of placing a 2 in front of H2O is chemically wrong — it changes what substance you're describing.
Historical insight: Lavoisier's discovery required sealed containers to capture gases. Before this, chemists thought burning released a mysterious substance called "phlogiston" into the air — mass appeared to decrease because the gas escaped unweighed.
Watch atoms rearrange — same colours appear on both sides · choose any reaction · atoms are never created or destroyed Interactive
03

Fireworks — Chemical Change in Action

Fireworks are a real-time demonstration of chemical change — metal salts undergoing combustion reactions that produce new substances and release energy as light. Each colour corresponds to a different metal salt:

Colour Metal salt Indicator of chemical change
RedStrontium compoundsColour change, gas evolved, temperature increase
GreenBarium compoundsColour change, gas evolved, temperature increase
BlueCopper compoundsColour change, gas evolved, temperature increase
YellowSodium compoundsColour change, gas evolved, temperature increase
🎆 Real-World Anchor — Fireworks: Fireworks demonstrate all five indicators of chemical change simultaneously — colour change, gas evolved, temperature change, and new oxide products formed. The original metal salt is consumed and cannot be recovered. This is the real-world anchor for this lesson and will reappear in Short Answer Q3.
Common error: The colour of a firework is not a physical property of the metal — it is produced by the chemical reaction. The metal itself may be grey or silver. Electron transitions during combustion produce the colour as electrons fall back to lower energy levels.

🧮 Worked Examples

Worked Example 1 — Classifying Physical and Chemical Changes

Stepwise
Classify each of the following as a physical or chemical change. Justify each answer by identifying whether a new substance is formed.
(a) Melting chocolate   (b) Burning natural gas   (c) Dissolving sugar in water   (d) Rust forming on iron
  1. 1
    (a) Melting chocolate
    Chocolate changes from solid to liquid but is still chemically chocolate. No new substance is formed. Physical change.
  2. 2
    (b) Burning natural gas
    Burning methane produces carbon dioxide and water vapour — new substances with different properties from methane. Chemical change.
  3. 3
    (c) Dissolving sugar in water
    Sugar molecules disperse through water but remain chemically sucrose. Can be recovered by evaporation. No new substance. Physical change.
  4. 4
    (d) Rust forming on iron
    Produces iron(III) oxide (Fe2O3), a new reddish-brown substance with different properties from grey iron metal. Chemical change.
✓ Answers (a) Physical — no new substance; (b) Chemical — CO2 and H2O formed; (c) Physical — sucrose unchanged; (d) Chemical — iron(III) oxide formed

Worked Example 2 — Identifying Indicators of Chemical Change

Stepwise
A student adds a piece of zinc metal to a test tube containing dilute sulfuric acid. They observe: the zinc gradually disappears, bubbles form vigorously, and the test tube becomes warm. Identify all indicators of chemical change present and name the products formed.
  1. 1
    Indicator 1 — Solid disappearing
    Zinc metal is consumed, indicating it has reacted and formed a new substance (not just dissolved physically).
  2. 2
    Indicator 2 — Gas evolved
    Bubbles forming — gas is evolved. Zinc reacting with sulfuric acid produces hydrogen gas (H2), confirmed by the "squeaky pop" test with a lit splint.
  3. 3
    Indicator 3 — Temperature increase
    The test tube becomes warm, indicating an exothermic chemical reaction releasing energy to the surroundings.
  4. 4
    Products and balanced equation
    Zinc sulfate (ZnSO4) is also formed in solution.
    Zn(s) + H2SO4(aq) → ZnSO4(aq) + H2(g)
✓ Answer Three indicators: solid disappearing (zinc consumed), gas evolved (hydrogen), temperature increase (exothermic). Products: ZnSO4(aq) and H2(g)

📝 How are you completing this lesson?

Physical or Chemical Change? Are new substances formed? Yes No Physical Change e.g. melting, boiling, dissolving Chemical Change e.g. burning, rusting, fizzing

🧪 Activities

🔎 Activity 1 — Spot + Fix

Finding the Error in Student Reasoning

Each student response below contains an error in classifying a change. Identify the error and write a corrected response.

  1. 1 Student A says: "When I dissolved salt in water and the water turned clear, that was a chemical change because the salt disappeared." Identify the error and correct it.

    Error: The student used "disappeared" as evidence of chemical change without checking whether a new substance was formed.
    Correction: Dissolving salt in water is a physical change. NaCl dissociates into Na⁺ and Cl⁻ ions in solution but remains chemically sodium chloride — no new substance is formed. The salt can be recovered by evaporating the water.
  2. 2 Student B says: "When ammonium nitrate dissolved in water, the beaker got really cold, so that proves it was a chemical change." Identify the error and correct it.

    Error: The student used temperature change alone as proof of a chemical change. This is insufficient — temperature change is an indicator, not a defining criterion.
    Correction: Dissolving ammonium nitrate in water is a physical change (endothermic). No new substance is formed — the NH₄⁺ and NO₃⁻ ions remain chemically ammonium nitrate in solution. The temperature change here results from the energy absorbed during dissolution, not from a chemical reaction.
  3. 3 Student C says: "Rusting and burning are different types of change — rusting is physical (it's just the surface changing colour) and burning is chemical." Identify the error.

    Error: The student misclassified rusting as physical because only the colour appears to change at the surface.
    Correction: Both rusting and burning are chemical changes — both produce new substances. Rusting produces iron(III) oxide (Fe₂O₃), a new substance with different properties from iron. The colour change at the surface is evidence of a new substance, not evidence of a physical change. Student C confused observable appearance with chemical identity.

Type your working below before revealing answers above:

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🔬 Activity 2 — Analyse + Connect

Fireworks: A Multi-Indicator Analysis

Analyse the firework scenario and answer the questions below. Connect your answers back to the theory from this lesson.

Scenario: A red firework (strontium nitrate — Sr(NO3)2) is ignited. Observers see a bright red flash of light, hear a bang, feel warmth from a distance, and notice a thin trail of white smoke (strontium oxide — SrO) remaining in the air.
Observation Indicator of chemical change? New substance responsible
Red flash of light and colour Your answer Your answer
Loud bang and gas released Your answer Your answer
Warmth felt at a distance Your answer Your answer
White smoke (SrO) remaining Your answer Your answer
Question A: Using the table above, explain in 2–3 sentences why the ignition of the firework is classified as a chemical change rather than a physical change.
Question B: The unburnt strontium nitrate is a white powder. After the firework, the remaining product is white strontium oxide (SrO). Explain why this observation supports the classification as a chemical change.

Complete the table and answer A and B below:

Complete the table and answer A and B in your workbook.

✏️ Complete the table and answer A and B in your workbook
Interactive — Physical vs Chemical Change Classifier
Revisit Your Thinking

Earlier you were asked: Are rusting and burning the same type of change? Is melting ice the same kind of change as burning wood?

The key insight: rusting and burning are both chemical changes — both produce new substances (iron(III) oxide; carbon dioxide and water) with different properties from the reactants. Melting ice is a physical change — water is still water, just in a different state. The test is never about appearance; it's always about whether new substances with different chemical properties are formed.

Now revisit your initial response. What did you get right? What has changed in your thinking?

Look back at your initial response in your book. Annotate it with what you now understand differently.

Annotate your initial response in your book
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Revisit Your Initial Thinking

Look back at what you wrote in the Think First section. What has changed? What did you get right? What surprised you?

Misconceptions to Fix

Wrong: A temperature change always means a chemical change has occurred.

Right: Temperature changes occur in both physical and chemical changes. Dissolving NaOH in water is exothermic but physical. A chemical change requires formation of a new substance with different properties. The definitive test is whether new chemical species are produced.

MC

Multiple Choice

5 random questions from a replayable lesson bank — feedback shown immediately

✍️ Short Answer

04

Extended Questions

UnderstandBand 3

8. Distinguish between a physical change and a chemical change. In your answer, explain two observable indicators that can suggest a chemical change has occurred and provide one example of each indicator. 4 MARKS

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✏️ Answer in your workbook
ApplyBand 4

9. A student adds marble chips (calcium carbonate, CaCO3) to a beaker of dilute hydrochloric acid (HCl). They observe: vigorous bubbling, the marble chips gradually disappearing, and the beaker becoming slightly warm. (a) Identify three indicators of chemical change present. (1 mark each) (b) Write a balanced chemical equation for this reaction. Include state symbols. (1 mark) 4 MARKS

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EvaluateBand 5

10. Fireworks produce brilliant colours through the combustion of metal salts. When a red firework (strontium nitrate, Sr(NO3)2) is ignited, observers see a red flash, hear an explosion, feel heat, and notice white strontium oxide (SrO) smoke. (a) Identify all observable indicators of chemical change present and, for each, name the new substance responsible. (3 marks) (b) Explain why a student who says "the firework just changed colour so it must be physical" is incorrect. Use at least two pieces of evidence. (2 marks) 5 MARKS

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✅ Comprehensive Answers

🔎 Activity 1 — Spot + Fix

1. Student A: Error — used "disappeared" as evidence without checking whether a new substance formed. Correction: Dissolving salt is physical; NaCl dissociates to Na⁺ and Cl⁻ but remains chemically the same; recoverable by evaporation.

2. Student B: Error — used temperature change alone as proof of chemical change. Correction: Temperature change is an indicator, not a defining criterion. Dissolving NH₄NO₃ is an endothermic physical change — no new substance is formed.

3. Student C: Error — misclassified rusting as physical because "only the surface changed colour." Correction: Rusting produces Fe₂O₃, a new substance — this is a chemical change. Colour change at the surface is evidence of a new substance, not evidence of a physical change.

🔬 Activity 2 — Fireworks Table

Row 1: Colour change — Yes, indicator of chemical change. New substance: excited electrons in strontium atoms releasing energy as red light (strontium oxide SrO formed)

Row 2: Gas evolved (explosion/bang) — Yes, indicator. New substances: CO₂ and NO₂ gases from decomposition of nitrate

Row 3: Temperature change (warmth felt) — Yes, indicator. Exothermic combustion releasing heat energy

Row 4: New product SrO visible as white smoke — Yes, indicator. SrO is a new solid substance with different properties from Sr(NO₃)₂

Question A: The ignition is a chemical change because new substances are formed (SrO, CO₂, NO₂) with different properties from the original strontium nitrate. Multiple indicators confirm this — gas evolved, colour change, temperature increase, and new solid product. The original substance is consumed and cannot be recovered.

Question B: The original Sr(NO₃)₂ is white powder; the product SrO is also white but is a chemically different substance. SrO has a different melting point, different reactivity with water, and different chemical formula. The fact that the product looks similar in colour does not mean it is the same substance — its chemical identity has changed, confirming a chemical change.

❓ Multiple Choice

1. D — The defining criterion for chemical change is the production of a new substance with different chemical properties. Temperature, colour, and bubbles are indicators but not the definition.

2. B — The copper sulfate was recovered unchanged; no new substance was produced. Applying heat to evaporate is a physical process here.

3. C — 2Mg + O₂ → 2MgO: left side has 2 Mg and 2 O; right side has 2 Mg and 2 O. Balanced. Option B has 2 O left and 1 O right (unbalanced). Option A uses O atoms not O₂ molecules.

4. A — Three indicators: bubbles (gas evolved = H₂), zinc disappears (solid consumed, chemical reaction), test tube warms (exothermic temperature change). The solution remaining colourless is not an indicator of change.

5. B — Dissolving NaCl is physical (NaCl unchanged, recoverable). Burning candle wax produces CO₂ and H₂O — chemical change.

6. C (Band 5 — Evaluate) — New substances NaOH(aq) and H₂(g) are formed. 2Na(s) + 2H₂O(l) → 2NaOH(aq) + H₂(g). This is fundamentally different from NaCl dissolving — the sodium atoms are consumed and incorporated into new compounds.

7. A (Band 6 — Create) — The strongest evidence combines: (1) conservation of mass check (sealed container), (2) testing chemical properties of the product — MgO has a different melting point (~2852°C vs Mg ~650°C), reacts differently with acid, and has different reactivity. Option B documents only one indicator; C documents only temperature; D attempts to prove the substance is unchanged (which would disprove chemical change).

📝 Short Answer Model Answers

Q8 (4 marks): A physical change alters the form or appearance of a substance without producing a new substance — the chemical identity remains the same [1]. A chemical change produces one or more new substances with different chemical properties — bonds are broken and formed [1]. Indicator 1 — gas evolved: bubbles/fizzing indicate a new gaseous product has formed; e.g. adding acid to marble chips produces CO₂ gas [1]. Indicator 2 — colour change: a new colour appears because the new substance absorbs different wavelengths of light; e.g. copper turning green as it oxidises to form copper carbonate [1]. Accept any two of the five indicators with valid examples.

Q9 (4 marks): (a) Indicator 1: gas evolved — vigorous bubbling indicates CO₂ gas produced [1]. Indicator 2: solid disappearing — marble chips consumed, indicating reaction forming new substances [1]. Indicator 3: temperature change — beaker becomes warm, indicating exothermic reaction [1]. (b) CaCO₃(s) + 2HCl(aq) → CaCl₂(aq) + H₂O(l) + CO₂(g) [1 — must be balanced with state symbols].

Q10 (5 marks): (a) Indicator 1: colour change (red flash) — new substance: excited strontium atoms emitting red light as electrons fall back; SrO formed [1]. Indicator 2: gas evolved (explosion/bang) — new substances: CO₂ and NO₂ gases from decomposition of NO₃⁻ [1]. Indicator 3: temperature change (heat felt) — exothermic combustion releases energy as heat [1]. (b) The student is incorrect because: first, a colour change is an indicator of chemical change (evidence a new substance is forming), not evidence of physical change [1]; second, the formation of white SrO smoke confirms a new substance with different chemical properties from the original Sr(NO₃)₂ has been produced — a defining criterion for chemical change [1].

Science Jump

Physical & Chemical Change

Climb platforms, hit checkpoints, and answer questions on Physical & Chemical Change. Quick recall from lessons 1–1.

Mark lesson as complete

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