Not all metals are created equal. Some are so reactive they will eagerly push others out of compounds, while barely reactive metals sit untouched. Discover the metal reactivity series, witness dramatic displacement reactions, and revisit neutralisation as a powerful reaction type in its own right.
Imagine you drop a shiny new iron nail into a blue copper sulfate solution.
Write down your predictions before reading on:
The more reactive metal wins
Reaction Rates
In a displacement reaction, a more reactive element pushes out (displaces) a less reactive element from its compound. The general pattern is:
A + BC → AC + B
where A is more reactive than B. This means A takes B's place in the compound.
At Stage 5, we focus on metal displacement in solutions. For example, if you place a strip of magnesium (very reactive) into copper sulfate solution, the magnesium displaces the copper. The blue solution fades as colourless magnesium sulfate forms, and reddish-brown copper metal deposits on the magnesium strip.
Your prediction tool
The reactivity series is a list of metals arranged from most reactive to least reactive. At Stage 5, the key metals to know are:
Most reactive
magnesium > aluminium > zinc > iron > tin > lead > copper > silver > gold
Least reactive
Any metal can displace any metal below it in the series. Magnesium displaces copper, zinc and iron. Zinc displaces copper and silver. But copper cannot displace zinc or magnesium.
| Reaction | Word equation | Observations |
|---|---|---|
| Mg in CuSO₄ | magnesium + copper sulfate → magnesium sulfate + copper | Blue solution fades; reddish-brown solid forms |
| Zn in CuSO₄ | zinc + copper sulfate → zinc sulfate + copper | Blue solution fades; reddish-brown solid forms |
| Fe in CuSO₄ | iron + copper sulfate → iron sulfate + copper | Blue solution fades; reddish-brown solid forms |
| Cu in AgNO₃ | copper + silver nitrate → copper nitrate + silver | Colourless solution turns blue; silver solid forms |
Acid + base → salt + water
Neutralisation is a reaction type in its own right. When an acid reacts with a base, they neutralise each other to produce a salt and water. The general word equation is:
acid + base → salt + water
Examples include hydrochloric acid reacting with sodium hydroxide to form sodium chloride (table salt) and water, and sulfuric acid reacting with copper oxide to form copper sulfate and water.
Neutralisation reactions are usually exothermic — they release heat. You can feel the test tube warm up when an acid and base react. They also typically cause a pH change from acidic or alkaline toward neutral (pH 7).
"Any metal can displace any other metal." No — only a more reactive metal can displace a less reactive one. Gold cannot displace zinc.
"A displacement reaction is the same as a decomposition reaction." No — displacement involves one element replacing another in a compound. Decomposition is one compound breaking apart.
Australia is one of the world's largest producers of iron ore and zinc. The reactivity series has direct industrial applications here. Galvanising is the process of coating iron or steel with a layer of zinc. Even if the zinc coating is scratched, the zinc (more reactive) will corrode preferentially, protecting the iron underneath. This is why galvanised steel is used for Australian fencing, roofing and outdoor structures.
In Australian mining, understanding the reactivity series helps engineers choose the best methods for extracting metals from their ores. More reactive metals like aluminium require electrolysis for extraction, while less reactive metals like copper can be extracted using simpler chemical methods.
1. What happens in a displacement reaction?
2. According to the reactivity series, which of these metals is the MOST reactive?
3. A magnesium strip is placed in copper sulfate solution. What would you observe?
4. Which of the following would NOT result in a displacement reaction?
5. Iron is coated with zinc (galvanising) to prevent rusting. Using the reactivity series, which is the best explanation for why zinc protects iron even when scratched?
1. Explain what a displacement reaction is and how the reactivity series helps predict whether a displacement will occur. 4 MARKS
2. A student places a zinc strip into copper sulfate solution. Describe the expected observations and explain the reaction using the reactivity series. 4 MARKS
3. Explain why galvanising iron with zinc protects the iron from rusting, even if the zinc coating is scratched. Use the reactivity series in your answer. 4 MARKS
Go back to your Think First answer. Has your understanding changed?
C — In a displacement reaction, a more reactive element replaces a less reactive element in a compound.
D — Magnesium is the most reactive metal in the list provided. Gold is the least reactive.
C — Magnesium is more reactive than copper, so it displaces copper from copper sulfate. The blue solution fades as colourless magnesium sulfate forms, and reddish-brown copper metal deposits on the magnesium strip.
D — Copper is less reactive than magnesium, so copper cannot displace magnesium from magnesium sulfate solution. No reaction occurs.
B — Zinc is more reactive than iron in the reactivity series. This means zinc will corrode (react with oxygen and water) preferentially, protecting the iron underneath. Even if scratched, the zinc continues to sacrifice itself.
Model answer: A displacement reaction is a reaction where a more reactive element replaces a less reactive element in a compound. The reactivity series helps predict displacement because it ranks metals from most reactive to least reactive. Any metal can displace any metal below it in the series. For example, zinc (above copper) can displace copper from copper sulfate, but copper (below zinc) cannot displace zinc from zinc sulfate.
Model answer: The expected observations are: the blue colour of the copper sulfate solution gradually fades as colourless zinc sulfate forms, and a reddish-brown solid (copper metal) deposits on the surface of the zinc strip. Using the reactivity series, zinc is more reactive than copper. This means zinc displaces copper from the copper sulfate solution. The word equation is: zinc + copper sulfate → zinc sulfate + copper.
Model answer: Galvanising protects iron because zinc is more reactive than iron in the reactivity series. When the iron is coated with zinc, the zinc reacts with oxygen and water in preference to the iron, preventing rust. Even if the zinc coating is scratched, the exposed zinc still protects the iron because zinc corrodes preferentially — it 'sacrifices' itself. This is called sacrificial protection and is widely used in Australian fencing, roofing and marine structures.
Test your knowledge of displacement reactions and the reactivity series. Predict outcomes, identify observations and blast your way to a high score!
Tick when you have finished all activities and checked your answers.