Chemical equations are the language of chemistry. They tell us exactly what reacts, what is produced, and in what proportions. In this lesson you will learn to write word equations, take your first steps into symbolic equations, and master the essential skill of balancing — making sure no atoms are created or destroyed.
Look at this symbolic equation:
H2 + O2 → H2O
Write down your answers before reading on:
The first step in describing reactions
Exothermic Endothermic
A word equation describes a chemical reaction using the names of substances. The reactants (starting substances) go on the left, and the products (new substances formed) go on the right, separated by an arrow:
reactant + reactant → product + product
Word equations are the foundation of chemical communication at Stage 5. Before using formulas, scientists always describe reactions in words to make sure everyone understands what is happening.
| Reaction type | Word equation example |
|---|---|
| Synthesis | magnesium + oxygen → magnesium oxide |
| Decomposition | calcium carbonate → calcium oxide + carbon dioxide |
| Combustion | methane + oxygen → carbon dioxide + water |
| Displacement | zinc + copper sulfate → zinc sulfate + copper |
| Neutralisation | hydrochloric acid + sodium hydroxide → sodium chloride + water |
Using formulas and counting atoms
A symbolic equation uses chemical formulas instead of names. For example, the reaction between hydrogen and oxygen to form water can be written as:
H2 + O2 → H2O
But is this balanced? Let's count atoms:
The oxygen atoms are not balanced. We cannot change the formula H2O to H2O2 because that would be a different substance (hydrogen peroxide). Instead, we place a coefficient (a number in front) to show more molecules:
2H2 + O2 → 2H2O
Now count again:
Both sides have 4 hydrogen and 2 oxygen. The equation is now balanced!
Step-by-step atom counting
Here is a worked example for balancing the reaction between magnesium and oxygen:
Step 1: Mg + O2 → MgO
Count: Left = 1 Mg, 2 O. Right = 1 Mg, 1 O. Oxygen is unbalanced.
Step 2: Try 2MgO on the right: Mg + O2 → 2MgO
Count: Left = 1 Mg, 2 O. Right = 2 Mg, 2 O. Magnesium is now unbalanced.
Step 3: Add 2Mg on the left: 2Mg + O2 → 2MgO
Count: Left = 2 Mg, 2 O. Right = 2 Mg, 2 O. Balanced!
State symbols tell us the physical state of each substance:
Example: 2Mg(s) + O2(g) → 2MgO(s)
"You can change subscripts to balance an equation." No — changing subscripts changes the substance. H2O is water; H2O2 is hydrogen peroxide. Only coefficients can be changed.
"A balanced equation is just for show — it doesn't matter if it's unbalanced." No — an unbalanced equation violates the law of conservation of mass. Atoms cannot be created or destroyed in chemical reactions.
Australia's mining and metallurgical industries rely heavily on balanced chemical equations. When BHP extracts iron from iron ore, engineers use balanced equations to calculate exactly how much coke (carbon) is needed to reduce the iron oxide, and how much carbon dioxide will be produced.
At the Tomago aluminium smelter near Newcastle, chemists use symbolic equations to understand the electrolysis of aluminium oxide. Balanced equations ensure that raw materials are used efficiently and waste is minimised. Without balanced equations, industrial chemistry would be guesswork — costing money and creating unnecessary pollution.
1. What does a word equation show?
2. In the equation H2 + Cl2 → 2HCl, what does the '2' in front of HCl mean?
3. What coefficients balance the equation __Mg + __O2 → __MgO?
4. How many oxygen atoms are on each side of 2H2 + O2 → 2H2O?
5. A student writes C + O2 → CO2 and says it is balanced. Another writes H2 + O2 → H2O and says it is balanced. Who is correct and why?
1. Explain the difference between a word equation and a symbolic equation. Give one example of each for the same reaction. 4 MARKS
2. Balance the equation for the reaction between nitrogen and hydrogen to form ammonia: N2 + H2 → NH3. Show your working by counting atoms on each side. 4 MARKS
3. A student argues that you can balance H2 + O2 → H2O by changing the formula to H2O2. Explain why this is incorrect and demonstrate the correct way to balance this equation. 4 MARKS
Go back to your Think First answer. Has your understanding changed?
B — A word equation shows the names of the reactants and products in a chemical reaction.
B — The '2' in front of HCl is a coefficient, meaning two molecules of hydrogen chloride are produced.
B — 2Mg + O2 → 2MgO is balanced: 2 Mg and 2 O on each side.
B — Left side has 2 oxygen atoms (from O2). Right side has 2 × 1 = 2 oxygen atoms (from 2H2O). The equation is balanced.
B — C + O2 → CO2 is balanced: 1 C and 2 O on each side. H2 + O2 → H2O is NOT balanced: 2 O on the left but only 1 O on the right. It should be 2H2 + O2 → 2H2O.
Model answer: A word equation uses the names of substances to describe a reaction. For example: hydrogen + oxygen → water. A symbolic equation uses chemical formulas and symbols instead of names. For the same reaction: H2 + O2 → H2O. Symbolic equations are more concise and allow chemists to balance reactions by counting atoms, while word equations are clearer for beginners and ensure everyone understands which substances are involved.
Model answer: In N2 + H2 → NH3, the left side has 2 nitrogen atoms and 2 hydrogen atoms. The right side has 1 nitrogen atom and 3 hydrogen atoms. To balance nitrogen, place a 2 in front of NH3: N2 + H2 → 2NH3. Now the right side has 2 nitrogen atoms and 6 hydrogen atoms. To balance hydrogen, place a 3 in front of H2: N2 + 3H2 → 2NH3. Final check: left = 2 N, 6 H; right = 2 N, 6 H. Balanced.
Model answer: Changing H2O to H2O2 is incorrect because H2O is water and H2O2 is hydrogen peroxide — they are completely different substances. In balancing, you can only change coefficients (numbers in front), never subscripts (small numbers in formulas). The correct way to balance H2 + O2 → H2O is: count atoms (2 H, 2 O on left; 2 H, 1 O on right). Place a 2 in front of H2O: H2 + O2 → 2H2O. Now right side has 4 H, 2 O. Place a 2 in front of H2: 2H2 + O2 → 2H2O. Now both sides have 4 H and 2 O.
Test your equation balancing skills. Count atoms, fix coefficients and blast your way to a high score!
Tick when you have finished all activities and checked your answers.